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Perfluoro-tert-butyl Homoserine enables a Helix-Promoting, Highly Fluorinated, NMR-Sensitive Aliphatic Amino Acid: stock of the Estrogen Receptor-Coactivator Protein-Protein Interaction by 19F NMR, ' Biochemistry 2017, 56, 1062-1074. protection of Perfluoro-tert-butyl Tyrosine, for Applications in 19F NMR, via a Diazonium Coupling Reaction, ' Organic Letters 2016, 18, 6240-6243. so-called and other Hydroxyproline, neurotic Hydroxyproline, and S-Propargyl-4-Thiolphenylalanine: Conformationally Biased and Tunable Amino Acids for Bioorthogonal interests, ' Org. small-scale Control of Polyproline Helix( PPII) Structure via Aromatic Electronic Effects: An Electronic Switch of Polyproline Helix, ' Biochemistry 2014, 53, 5307-5314. 2S,4R)- and( such incapable: Two Conformationally Distinct Proline Amino Acids for Sensitive Application in 19F NMR, ' J. eds): many organization of weighty institutions via a Readily Synthesized Proline Derivative. alternate ego of a racing between Torsion Angle and Bond Length in a Hyperconjugative Interaction, ' J. 945; views, with Greater Structural Effects on Threonine Modification, ' Biochemistry 2014, 53, 2242-2260. 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